## Colloquium-Pawan Singh Takhar (University of Illinois)-A mixture theoretic approach for coupling biopolymer thermomechanics with fluid and species transport

Mathematics - Colloquium

Friday, April 11, 2014

11:00 AM-12:00 PM

Stratton Hall

203

ABSTRACT: The hybrid mixture theory was used to obtain the two-scale unsaturated transport and thermomechanical equations for biomaterials. The two-scale laws of conservation of mass, momentum, energy and entropy were utilized, the constitutive theory was formulated and the entropy inequality was exploited to obtain various equilibrium, near- equilibrium and non-equilibrium relations. The system was treated as poro-viscoelastic with viscoelastic biopolymers interacting with the viscous liquid phases (water and oil) at pore-scale. The interaction of hydrophilic and hydrophobic biopolymers with the water and oil phases was included. The gas phase was considered as a mixture of air and water vapors, which exchanged mass with the liquid water due to evaporation/condensation away from equilibrium. The exploitation of entropy inequality resulted in temporally non-local generalized Darcy’s law relations for water and oil phases, near-equilibrium swelling and capillary pressure relations, generalized stress relations, near-equilibrium Gibbs free energy relation and the rate of evaporation relation. The generalized Darcy’s law relations include novel integral terms with long-memory effects. These can describe the effect of biopolymer-fluid interaction on both Darcian and non-Darcian modes of fluid transport depending upon the state of the biomaterial (glassy, rubbery or glass-transition). The resulting transport laws for various phases include the cross-effect terms in form of volume fraction gradients. The system of equations can be used to predict quality changes in biopolymers during processing of biomaterials for a wide range of industrial applications.

Suggested Audiences:
Adult, College

E-mail:
ma-chair@wpi.edu

Last Modified: April 10, 2014 at 11:06 AM

## Colloquium-Pawan Singh Takhar (University of Illinois)-A mixture theoretic approach for coupling biopolymer thermomechanics with fluid and species transport

Mathematics - Colloquium

Friday, April 11, 2014

11:00 AM-12:00 PM

Stratton Hall

203

ABSTRACT: The hybrid mixture theory was used to obtain the two-scale unsaturated transport and thermomechanical equations for biomaterials. The two-scale laws of conservation of mass, momentum, energy and entropy were utilized, the constitutive theory was formulated and the entropy inequality was exploited to obtain various equilibrium, near- equilibrium and non-equilibrium relations. The system was treated as poro-viscoelastic with viscoelastic biopolymers interacting with the viscous liquid phases (water and oil) at pore-scale. The interaction of hydrophilic and hydrophobic biopolymers with the water and oil phases was included. The gas phase was considered as a mixture of air and water vapors, which exchanged mass with the liquid water due to evaporation/condensation away from equilibrium. The exploitation of entropy inequality resulted in temporally non-local generalized Darcy’s law relations for water and oil phases, near-equilibrium swelling and capillary pressure relations, generalized stress relations, near-equilibrium Gibbs free energy relation and the rate of evaporation relation. The generalized Darcy’s law relations include novel integral terms with long-memory effects. These can describe the effect of biopolymer-fluid interaction on both Darcian and non-Darcian modes of fluid transport depending upon the state of the biomaterial (glassy, rubbery or glass-transition). The resulting transport laws for various phases include the cross-effect terms in form of volume fraction gradients. The system of equations can be used to predict quality changes in biopolymers during processing of biomaterials for a wide range of industrial applications.

Suggested Audiences: Adult, College

E-mail: ma-chair@wpi.edu

Last Modified: April 10, 2014 at 11:06 AM